全文获取类型
收费全文 | 2292篇 |
免费 | 110篇 |
国内免费 | 17篇 |
专业分类
化学 | 1657篇 |
晶体学 | 31篇 |
力学 | 31篇 |
数学 | 134篇 |
物理学 | 566篇 |
出版年
2023年 | 22篇 |
2021年 | 21篇 |
2020年 | 37篇 |
2019年 | 57篇 |
2018年 | 50篇 |
2017年 | 23篇 |
2016年 | 46篇 |
2015年 | 73篇 |
2014年 | 67篇 |
2013年 | 141篇 |
2012年 | 136篇 |
2011年 | 136篇 |
2010年 | 102篇 |
2009年 | 94篇 |
2008年 | 150篇 |
2007年 | 155篇 |
2006年 | 150篇 |
2005年 | 133篇 |
2004年 | 145篇 |
2003年 | 104篇 |
2002年 | 65篇 |
2001年 | 49篇 |
2000年 | 24篇 |
1999年 | 25篇 |
1998年 | 11篇 |
1997年 | 13篇 |
1996年 | 12篇 |
1995年 | 17篇 |
1994年 | 20篇 |
1993年 | 40篇 |
1992年 | 29篇 |
1991年 | 19篇 |
1990年 | 15篇 |
1989年 | 16篇 |
1988年 | 14篇 |
1987年 | 10篇 |
1986年 | 14篇 |
1985年 | 17篇 |
1984年 | 12篇 |
1983年 | 8篇 |
1982年 | 11篇 |
1981年 | 18篇 |
1980年 | 12篇 |
1979年 | 13篇 |
1978年 | 12篇 |
1977年 | 8篇 |
1976年 | 9篇 |
1975年 | 15篇 |
1974年 | 13篇 |
1973年 | 9篇 |
排序方式: 共有2419条查询结果,搜索用时 15 毫秒
21.
The transient heat transfer behavior in the case of heat removal from a cylindrical heat storage vessel packed with spherical particles was investigated experimentally for various factors (flow rate, diameter of spherical particles packed, temperature difference between flowing cold air and spherical particles accumulating heat, and physical properties of spherical particles). The experiments were covered in ranges of Reynolds number based on the mean diameter of spherical particles packed Red = 10.3–2200, porosity?=0.310 to 0.475, ratio of spherical particle diameter to cylinder diameterd/D = 0.0075–0.177 and ratio of length of the cylinder to cylinder diameterL/D=2.5–10. It was found that especially the flow rate and the dimension of spherical particles played an important role in estimating the transient local heat transfer characteristics near the wall of the cylindrical vessel in the present heat storage system. As flow rate and diameter of spherical particles were increased under a given diameter of the cylinder heat storage vessel, the mean heat transfer coefficient between the flow cold air and the hot spherical particles increased and the time period to finish removing heat from the vessel reduced. In addition, the useful experimental correlation equations of mean heat transfer coefficient between both phases and the time period to finish removing heat from the vessel were derived with the functional relationship of Nusselt numberNu d=f [modified Prandtl numberPr * (d/D), Red) and Fourier numberFo = f(d/D, L/D, Pr*, Red). 相似文献
22.
Hiroki Matsunaga Hiroto Habu Atsumi Miyake 《Journal of Thermal Analysis and Calorimetry》2013,113(3):1387-1394
Ammonium dinitramide (ADN) is one of the several promising new solid propellant oxidizers. ADN is of interest because its oxygen balance and energy content are high, and it also halogen-free. One of the most important characteristics of a propellant oxidizer, however, is stability and ADN is known to degrade to ammonium nitrate (AN) during storage, which will affect its performance. This study focused on the effects of aging on the thermal decomposition mechanism of ADN. The thermal behaviors of ADN and ADN/AN mixtures were studied, as were the gases evolved during their decomposition, using differential scanning calorimetry (DSC), thermogravimetry–differential thermal analysis-infrared spectrometry (TG–DTA-IR), and thermogravimetry–differential thermal analysis-mass spectrometry (TG–DTA-MS). The results of these analyses demonstrated that the decomposition of ADN occurs via a series of distinct stages in the condensed phase. The gases evolved from ADN decomposition were N2O, NO2, N2, and H2O. In contrast, ADN mixed with AN (to simulate aging) did not exhibit the same initial reaction. We conclude that aging inhibits early stage, low temperature decomposition reactions of ADN. Two possible reasons were proposed, these being either a decrease in the acidity of the material due to the presence of AN, or inhibition of the acidic dissociation of dinitramic acid by NO 3 ? . 相似文献
23.
Tomoyuki MIYAZAKI Hiroki ABE Hiroyuki UCHIDA Takuya TAKAHASHI 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2021,97(1):1
Psychiatric and neurological disorders severely hamper patient’s quality of life. Despite their high unmet needs, the development of diagnostics and therapeutics has only made slow progress. This is due to limited evidence on the biological basis of these disorders in humans. Synapses are essential structural units of neurotransmission, and neuropsychiatric disorders are considered as “synapse diseases”. Thus, a translational approach with synaptic physiology is crucial to tackle these disorders. Among a variety of synapses, excitatory glutamatergic synapses play central roles in neuronal functions. The glutamate α-amino-3-hydroxy-5-methyl-4-isoxazole propionic acid receptor (AMPAR) is a principal component of glutamatergic neurotransmission; therefore, it is considered to be a promising translational target. Here, we review the limitations of current diagnostics and therapeutics of neuropsychiatric disorders and advocate the urgent need for the promotion of translational medicine based on the synaptic physiology of AMPAR. Furthermore, we introduce our recent translational approach to these disorders by targeting at AMPARs. 相似文献
24.
Dr. Yoshifumi Sasano Dr. Yohei Haketa Hiroki Tanaka Dr. Nobuhiro Yasuda Prof. Ichiro Hisaki Prof. Hiromitsu Maeda 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(27):6712-6717
Phenyl groups were introduced at the β-positions proximal to the meso-hydroxy moiety in hydroxyporphyrin NiII complexes by oxidized BINAP PdII complexes. Ion-pairing assemblies of deprotonated π-electronic anions, anionic site of which was stabilized by the introduced phenyl moieties with a bulky cation, were formed. They showed charge-by-charge assemblies, assembly modes of which were modulated by the anionic building units. 相似文献
25.
Shigekazu Ito Hiroki Sugiyama Masaaki Yoshifuji 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4-5):785-788
1-(2,4,6-Tri-tert-butylphenyl)-2-phosphaethyne (1) was allowed to react with 0.5 equiv of an alkyllithium and subsequently with an alcohol to afford a bulky 1,3-diphosphacyclobutene, and its structure and coordination properties on transition metals were investigated. On the other hand, 1 was allowed to react with an alkyllithium and iodomethane to form a stable biradical, 1,3-diphosphacyclobutane-2,4-diyl. 相似文献
26.
D. -J. Qian H. Nakahara K. Fukuda K. -Z. Yang 《Journal of Dispersion Science and Technology》2013,34(3):1031-139
Monolayers of europium complexes on water surface have been directly visualized in the gas-liquid expanded region at different temperatures using Brewster angle microscopy (BAM). The film texture with network patterns of the complex (C18)2 Eu(DBM)4 and hs evolution with time and temperature of the subphase were examined. The average linear cell dimension and the polygon areas have been analyzed as a function of time and the temperature. The mechanism of the domain growth is qualitatively discussed. 相似文献
27.
Two kinds of polyelectrolytes containing maleic acid component (MA copolymers), i.e., poly(styrene-alt-maleic acid) (PSMA) and poly(vinyl methyl ether-alt-maleic acid) (PVMEMA), were investigated on their polymer chain dimensional changes in solution, and also in gel phase for the latter, as a function of the polymer charge density or pH of the (immersing) solution. Being different from common poly(carboxylic acid)s such as poly(acrylic acid), both of the MA copolymers showed maximum in the reduced viscosity or the gel size with increasing the charge density or the solution pH. The maximum in the reduced viscosity was much more significant for PSMA than PVMEMA. To see if intramolecular hydrogen bond between a pair of dissociated and undissociated carboxyl groups in an MA residue contributes to the emergence of the peak or not, similar measurements were performed also in the presence of concentrated urea (5 M). Almost the same values were obtained up to the peak position for the reduced viscosity and the gel swelling degree with increasing pH of the (immersing) solutions, which strongly suggested that the supposed effect is negligible, if any. All the results including those for PVMEMA system were interpreted in terms of the ionomer-like conformational change (ion cluster formation) of polyelectrolytes that has been often observed when the polymer charges are in rather less polar circumstances. 相似文献
28.
29.
30.
Dr. Tatsuya Takimoto Prof. Hideaki Sasaki Prof. Hirohito Tsue Dr. Hiroki Takahashi Prof. Alexander D. MacKerell Jr. Ayumi Nakamura Katsuya Nakano Eori Okazaki Tatsuki Betsuyaku Ryosuke Tachibana Dr. Kazuhito Hioki Dr. Ozge Yoluk Dr. Sunhwan Jo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(5):1648-1654
A simple approach to the synthesis of heterocyclophane consisting of two 4,4’-bithiazoles has been developed in mild conditions. The heterocyclophane with two short chains was conveniently prepared by Hantzsch thiazoles synthesis using the reaction of 3-tert-butoxycarbonyl-3-azapentanethiocarboxamide with 1,4-dibromobutane-2,3-dione in methanol under reflux for only 15 min. Amino groups at the linkers of this heterocyclophane can be functionalized to give acylated and carbamate derivatives. Their properties as protein kinase inhibitors were investigated, and one of the heterocyclophanes exhibited specific anti-activity for c-mesenchymal epithelial transition factor (IC50=603 nm ), among seven types of protein kinases investigated. The computational site identification by ligand competitive saturation method was used to determine why the one heterocyclophane exhibited strong anti-activity for c-mesenchymal epithelial transition factor. 相似文献